Chemical Silver Clock

The formation of a white precipitate which becomes yellow and then black

Scientific name: The formation of silver iodate followed by reduction to iodide. Further, the free iodine is released which forms an iodine-starch complex.

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Safety

Wear eye protection goggles.

Always follow general safety recommendations. Please note that conducting chemistry experiments you must comply with the relevant legal procedures in your country.

Reaction formula

AgNO3 + KIO3 → AgIO3 + KNO3

2 AgIO3 + 6 Na2S2O5 → 2 AgI + 6 Na2SO4 + 6 SO2

2 AgI → 2 Ag + I2

Step-by-step instruction

  1. First, it is necessary to prepare three solutions, in large beakers. Achieve a complete dissolution of the components in each cup.

1) Add 20 ml of distilled water to 0.7 g of sodium metabisulfite. Measure volumes using measuring cylinders.

2) Pour 0.5 g of potassium iodate into a beaker and add 35 ml of water. Due to the low solubility in water, potassium iodate solution may be heated on a hot plate. Add a small amount of pre-cooked starch paste solution. Add 120 more ml of water.

3) Take a sample of silver nitrate (0.17 g). Then add 40 ml of distilled water.

  1. To perform the reaction mix all three solutions. During the reaction, the mixture must be regularly stirred with a glass rod.

Scientific background

The appearance of the white precipitate at the start is due to an ordinary ion exchange reaction between silver nitrate and potassium iodate which leads to the formation of silver iodate.

Sodium metabisulfite has reducing properties, which allow it to reduce iodate to iodide. Thus, the solution becomes yellow.

Silver iodide is an unstable compound and may decompose to simple substances. (This property has been used in photography.) Isolated free iodine forms a stable complex with starch that has a black color.

Danger:
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Difficulty:

Published on 15 May 2015

  • Fire
  • Heating with fire
  • Explosion
  • Poisoned gas
  • Organic
  • Electricity
  • Solution
  • Oxidation reduction
  • Color change
  • Precipitate
  • Gassing
  • Catalyst